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Use of the plant Bellardia trixago for the enantiospecific synthesis of odorant products
Authors:Barrero Alejandro F  Herrador M Mar  Arteaga Pilar  Castillo Alexis  Arteaga Alejandro F
Affiliation:Department of Organic Chemistry, Institute of Biotechnology, Faculty of Science, University of Granada, Campus de Fuente Nueva, s/n, 18071 Granada, Spain. afbarre@ugr.es
Abstract:
An easy procedure to obtain extracts enriched in trixagol monomalonylesther (1) from aerial parts of the plant Belladia trixago chemotype Trix was developed. Preparation of (+)-dihydro-gamma-ionone (4) was carried out directly from the extracts with good yields by selective oxidation. Other interesting odorant products as alpha-ambrinol (5), ambraldehyde (6) and the tricyclic compound 7 were synthesized very efficiently using (4) as intermediate.
Keywords:
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