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3种树脂对水溶液中单宁吸附性能的比较研究
引用本文:孙越,童建,李爱民,张全兴.3种树脂对水溶液中单宁吸附性能的比较研究[J].离子交换与吸附,2007,23(6):512-518.
作者姓名:孙越  童建  李爱民  张全兴
作者单位:1. 东南大学土木工程学院,南京,210096
2. 江苏省水文水资源勘测局,南京,210029
3. 污染控制与资源化研究国家重点实验室,南京大学环境学院,南京,210093
摘    要:通过静态吸附实验,研究了大孔吸附树脂NG-8、胺基化大孔吸附树脂NG-9和胺基化超高交联大孔吸附树脂NDA-99对水溶液中单宁的吸附行为特性.结果表明,3种树脂对单宁的吸附均符合Langmuir等温吸附方程,树脂对单宁的吸附容量NG-9>NG-8>NDA-99;吸附过程符合准二级动力学方程,吸附速率常数NG-8>NG-9>NDA-99.树脂的孔结构与表面化学性质是影响树脂吸附性能的重要因素.

关 键 词:吸附树脂  吸附  单宁  热力学  动力学
文章编号:1001-5493(2007)06-0512-07
修稿时间:2007年1月15日

STUDY ON ADSORPTION BEHAVIORS OF TANNIN FROM AQUEOUS SOLUTION ON THREE POLYMERIC RESINS
SUN Yue,TONG Jian,LI Aimin,ZHANG Quanxing.STUDY ON ADSORPTION BEHAVIORS OF TANNIN FROM AQUEOUS SOLUTION ON THREE POLYMERIC RESINS[J].Ion Exchange and Adsorption,2007,23(6):512-518.
Authors:SUN Yue  TONG Jian  LI Aimin  ZHANG Quanxing
Abstract:Adsorption behavior of tannin from aqueous solution by the macroporous polymeric resin NG-8,aminated hypercrosslinked polymeric resin NDA-99 and aminated macroporous polymeric resin NG-9 was studied through static experiments.The empirical Langmuir equation was successfully employed to describe the adsorption process and the adsorption capacities towards tannin increase in the following order:NG-9 > NG-8 > AH-1.The adsorption rate implied a pseudo-second order kinetic mechanism and the value of rate constant of the tested resins in the following order:NG-8 > NG-9 > NDA-99.The results showed that the pore size distribution and the tertiary amino group on the polymer played a significant role in tannin adsorption performance.
Keywords:Polymeric resin  Adsorption  Tannin  Thermodynamics  Kinetics
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