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α-Funktionelle 2-Methylphenylphosphane, 2-(HE?CH2)?C6H4?PH2 (E = O,NR, PH). II. Komplexbildungsverhalten mit den Metallcarbonylen des Cr,Mo, W
Authors:Jutta Kalbitz  Elke Leißring  Harry Schmidt
Abstract:α-Functionalized 2-Methyl Phenylphosphines, 2-(HE? CH2)? C6H4? PH2 (E = O, NR, PH) II. Coordination Behaviour with Metal Carbonyles of Cr, Mo, W The preparation of different carbonyl substituted coordination compounds (M: Cr, Mo, W) of the phosphines 2-(HE? CH2)C6H4? PH2 (E = O, NPh, PH) is described. In one case, after deprotonation of a PH2 group a phosphine/phosphide migration of a W(CO)5 fragment is detected.
Keywords:Carbonyl coordination compounds  α  -Functionalized 2-methyl phenylphosphines  W(CO)5 shift
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