Abstract: | Metal Complexes of Dyes. Phosphine-Nickel, Palladium, Platinum Complexes and Pentamethylcyclopentadienyl Rhodium and Iridium Complexes of 2,2′-Dihydroxyazoarenes The terdentate dianions of 2,2′-dihydroxyazobenzene (L1H), 1-(2-hydroxy-4-nitrophenylazo)-2-naphthol (L2H), 1-(2-hydroxy-5-nitrophenylazo)-2-naphthol (L3H) and 1-phenyl-3-methyl-4-(2-hydroxy-5-nitrophenylazo)-5-pyrazolone (L4H) form with chloro bridged complexes (R3P)MCl2]2 (M = Pd, Pt; R = Ph, nBu), (n5-C5Me5)MCl2]2 (M = Rh, Ir) and with (nBu3P)2NiCl2 the metal dye complexes (R3P)ML (M = Ni, Pd, Pt) and (C5Me5)ML (M = Rh, Ir). The structures of (Ph3P)PtL1 and (nBu3P)PdL3 have been determined by X-ray diffraction. For the complexes (n5-C5Me5)ML (M = Rh, Ir) with asymmetric metal centers two diastereoisomers are detected by nmr spectroscopy which points to the ?hydrazone”? form of the azo ligand with a pyramidalized N-atom. |