| Abstract: | Electrocrystallization of Fullerides The fullerides P(C6H5)4C60 · P(C6H5)4Cl, P(C6H5)4C60 · P(C6H5)4Br und As(C6H5)4C60 · As(C6H5)4Cl have been prepared by electrocrystallization. Single crystal structure determinations have shown them to be isostructural in space group I4/m with lattice constants a = 12.5731(9), c = 20.142(3) Å; a = 12.5378(10), c = 20.606(5) Å; a = 12.6003(11), c = 20.377(4) Å, respectively. Spectroscopic and magnetic investigations prove the existence of a C60? anion, showing orientational disorder in all three fullerides. |
