Ethers as ligands. Part V(1). Metal(II)-diglyme and -pentaglyme solvates |
| |
| Authors: | Willem L. Driessen Marinus den Heijer Nico van Gils Willem L. Groeneveld |
| |
| Affiliation: | (1) Gorlaeus Laboratories of the State University of Leiden, P. O. Box 9502, 2300 RA Leiden, The Netherlands |
| |
| Abstract: | ![]()
Summary Eighteen new coordination compounds are reported with diglyme (dgm) and pentaglyme (pgm) as ligands:viz. [M(dgm)2](SbCl6)2 with M=MgII, CaII, SrII, MnII, FeII, CoII, NiII, CuII, and ZnII; [M(pgm)](SbCl6)2 with M=MnII, FeII,CoII, NiII, CuII, and ZnII; and [M(pgm)](SbCl6)2 · H2O with M=MgII, CaII, and SrII. The metal(II) ions are hexacoordinated by the ether-oxygens of two diglyme molecules or of one pentaglyme molecule. The coordinated diglyme molecules are in the TGTT¯GT conformation. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
