首页 | 本学科首页   官方微博 | 高级检索  
     


Fast initial decay of molecular excitations at insulator surfaces
Authors:Wang Neng-Ping  Rohlfing Michael  Krüger Peter  Pollmann Johannes
Affiliation:Institut für Festk?rpertheorie, Universit?t Münster, 48149 Münster, Germany.
Abstract:
We investigate the initial decay of electron-hole excitations in a molecular layer after adsorption on an insulator substrate surface. This is done within ab initio many-body perturbation theory by calculating the time propagation of excited two-particle states. For a CO monolayer adsorbed on the MgO(001) surface we find very fast decay processes with lifetimes that are about 5 times shorter than the transfer of single charge carriers. This is due to a strong coupling of the molecular excitations to charge-transfer-exciton states between the adlayer and the substrate.
Keywords:
本文献已被 PubMed 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号