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Preparation of MXene-Cu2O nanocomposite and effect on thermal decomposition of ammonium perchlorate
Affiliation:1. Université Paul Sabatier, CIRIMAT UMR CNRS 5085, 118 route de Narbonne, 31062 Toulouse, France;2. Réseau sur le Stockage Electrochimique de l''Energie (RS2E), FR CNRS 3459, France;3. Department of Materials Science and Engineering and A. J. Drexel Nanomaterials Institute, Drexel University, Philadelphia, PA 19104, USA
Abstract:
MXenes are novel graphene-like 2-D materials. Cu2O is an effective additive for thermal decomposition of ammonium perchlorate (AP). We reported the synthesis of MXene (Ti3C2), Cu2O and MXene-Cu2O respectively. The samples were characterized by means of X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). Results indicate that the MXene is composed of lots of nano-sheets and the thickness is 30 ± 10 nm, and Cu2O nanoparticles nucleate and grow heterogeneously directly on the surface of MXene. The effect of these MXene, Cu2O and MXene-Cu2O samples on the thermal decomposition of AP were investigated using TG-DSC. The results revealed that MXene-Cu2O have a great influence on the thermal decomposition of AP than that of pure MXene and Cu2O.
Keywords:MXene  Nanocomposite  Microstructure  Thermal analysis
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