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Chromato-mass-spectrometric identification using partition coefficients in the system of hexane-2,2,2-trifluoroethanol
Authors:I. G. Zenkevich
Affiliation:1. Chemistry Department, St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia
Abstract:An additional characteristic of organic compounds, the partition coefficients in the heterophase solvent system n-hexane-2,2,2-trifluoroethanol, is shown to be useful for refining the results of chromatographic and gas chromatography-mass spectrometric identification. This opportunity is the most important for compounds that were not yet characterized by either mass spectra or chromatographic retention indices.
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