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An investigation of the role of the disparate redox states of the tetrathiafulvalene unit in modulating hydrogen bonding interactions in solution |
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| Authors: | Alan S.F. BoydGraeme Cooke Florence M.A. DuclairoirVincent M. Rotello |
| Affiliation: | a The Centre for Biomimetic Design and Synthesis, Department of Chemistry, William H. Perkin Building, School of Engineering and Physical Sciences, Heriot-Watt University, Riccarton, Edinburgh EH14 4AS, UK b Department of Chemistry, University of Massachusetts at Amherst, Amherst, MA 01002, USA |
| Abstract: | We have investigated the electrochemically controlled hydrogen bonding interactions between tetrathiafulvalene host 3 and guests 4 or 5. Stabilisation of the 3+  state is dependent upon the nature of the guest species, whereas both guests prevent precipitation of the electrochemically generated 32+ species at the working electrode via hydrogen bonded molecular recognition processes. |
| Keywords: | tetrathiafulvalene recognition electrochemistry |
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