N-Bromosuccinimide-dibenzoyl peroxide/azabisisobutyronitrile: a reagent for Z- to E-alkene isomerization |
| |
| Authors: | MdMerajuddin BaagAnirban Kar Narshinha P Argade |
| |
| Institution: | Division of Organic Chemistry (Synthesis), National Chemical Laboratory, Pashan, Pune 411 008, India |
| |
| Abstract: | N-Bromosuccinimide-dibenzoyl peroxide/azobisisobutyronitrile is used to carry out several types of Z- to E-alkene isomerizations. The NBS-bromination conditions are sufficient for both allylic bromination and alkene isomerization. When the allylic hydrogens are not available in substrates, only the isomerization of the alkene takes place. The present conditions for isomerization of carbon-carbon double bonds are mild and efficient. |
| |
| Keywords: | isomerization NBS-bromination carbon-carbon double bonds |
| 本文献已被 ScienceDirect 等数据库收录！ |
