Synthesis of 4-functionalized terdendate pyridine-based ligands |
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| Authors: | Tina VermondenDanuta Branowska Antonius TM Marcelis Ernst JR Sudhölter |
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| Institution: | a Laboratory of Organic Chemistry, Contribution from the Dutch Polymer Institute/Wageningen University, Dreijenplein 8, 6703 HB Wageningen, The Netherlands
b University of Podlasie, ul.3-go Maja 54, 08-110, Siedlce, Poland |
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| Abstract: | Four different 4-functionalised pyridine-based ligands were synthesized with aminomethyl, oxazolinyl, pyrazolyl and methylimidazolyl groups at the 2- and 6-position. The nitrogens of these groups together with the pyridine nitrogen can act as terdendate ligands for metal ions. Synthetic handles on the 4-position of the pyridine group were introduced via ether or ester bonds leading to monofunctional, bifunctional and amphiphilic ligands. |
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| Keywords: | terdendate ligand coordination supramolecular surfactant |
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