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Chemical reactivity of [1,2,3]triazolo[1,5-a]- and [1,5-c]-pyrimidinium salts
Authors:Sándor Bátori  Eszter Gács-BaitzSándor Bokotey  András Messmer
Institution:a Chinoin Pharmaceutical and Chemical Works Co, Ltd., P.O. Box 110, H-1325 Budapest, Hungary
b Chemical Research Center, Institute of Chemistry, Hungarian Academy of Sciences, P.O. Box 17, H-1525 Budapest, Hungary
Abstract:The chemical reactivity of the 1,2,3]triazolo1,5-a]- and 1,5-c]-pyrimidinium salts towards morpholine, water and sodium methoxide have been studied. Among others, new 1-aza and 2-azabutadienes substituted by a 1,2,3]-triazole ring were obtained in the course of the opening of the positively charged pyrimidine ring.
Keywords:1-azadienes  2-azadienes  vinamidines  ring opening  reactivity of pyrimidinium salts
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