Chemical reactivity of [1,2,3]triazolo[1,5-a]- and [1,5-c]-pyrimidinium salts |
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Authors: | Sándor Bátori Eszter Gács-BaitzSándor Bokotey András Messmer |
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Institution: | a Chinoin Pharmaceutical and Chemical Works Co, Ltd., P.O. Box 110, H-1325 Budapest, Hungary b Chemical Research Center, Institute of Chemistry, Hungarian Academy of Sciences, P.O. Box 17, H-1525 Budapest, Hungary |
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Abstract: | The chemical reactivity of the 1,2,3]triazolo1,5-a]- and 1,5-c]-pyrimidinium salts towards morpholine, water and sodium methoxide have been studied. Among others, new 1-aza and 2-azabutadienes substituted by a 1,2,3]-triazole ring were obtained in the course of the opening of the positively charged pyrimidine ring. |
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Keywords: | 1-azadienes 2-azadienes vinamidines ring opening reactivity of pyrimidinium salts |
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