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Chemoselective synthesis of stable phosphorus ylides containing a β-amino group
Authors:Mohammad Reza Islami  Zahra HassaniHassan Sheibani  Bahareh AbdolahzadehNazanin Etminan
Institution:Department of Chemistry, Shahid Bahonar University of Kerman, Kerman 76169, Iran
Abstract:A facile and chemoselective one-pot synthesis of stable phosphorus ylides containing a β-amino group has been developed via reaction of triphenylphosphine, dialkyl acetylenedicarboxylate and 1,2-phenylenediamine in the presence of phenol or 2-aminophenol on its own at ambient temperature.
Keywords:stable phosphorus ylides  1  2-phenylenediamine  phosphoranes
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