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Chiral ditopic receptors. Application to palladium-catalyzed allylic alkylation
Authors:Jean BourguignonUlf Bremberg  Georges DupasKristina Hallman  Lars HagbergLaurent Hortala  Vincent LevacherSerghey Lutsenko  Emmanuel MacedoChristina Moberg  Guy QuéguinerFredrik Rahm
Institution:a IRCOF, INSA, Laboratoire de Chimie Organique Fine et Hétérocyclique, UMR 6014, BP 08, F 76131 Mt St Aignan, France
b Department of Chemistry, KTH, Organic Chemistry, SE 100 44 Stockholm, Sweden
Abstract:Chiral pyridinooxazoline, quinolinooxazoline, bis(oxazolino)pyridine (pybox), and bisoxazoline (box) derivatives containing crown ether residues were prepared. Some of the ligands were assessed in substrate binding studies and in palladium catalyzed allylic alkylations.
Keywords:chiral  ligand  ditopic  crown ether  oxazoline  copper  palladium
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