An expedient preparation of Stryker's reagent |
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| Authors: | Pauline Chiu Zhengning LiKelvin C.M. Fung |
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| Affiliation: | Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, PR China |
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| Abstract: | A convenient and efficient preparation of Stryker's reagent, [Ph3PCuH]6, under homogeneous conditions using silanes as the reducing agent is detailed. The reaction time can be reduced to 1-2 h, and high yields of Stryker's reagent can be routinely achieved. The same method has been extended to the synthesis of [Ph3PCuD]6 using Ph2SiD2. |
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| Keywords: | Stryker's reagent copper and compounds silicon and compounds conjugate reduction |
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