Synthesis of quaternary allylammonium salts via ring opening of 1-benzyl-2-(bromomethyl)aziridines |
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| Authors: | Matthias D'hoogheWillem Van Brabandt Norbert De Kimpe |
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| Institution: | Department of Organic Chemistry, Faculty of Agricultural and Applied Biological Sciences, Ghent University, Coupure Links 653, B-9000 Ghent, Belgium |
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| Abstract: | Treatment of 1-benzyl-2-(bromomethyl)aziridine, and some aryl substituted analogues, with an excess of iodomethane resulted in N-allyl-N-benzyl-N,N-dimethylammonium salts, in good yields. These quaternary allylammonium salts are of importance in different fields, from organic synthesis and polymeric chemistry to agricultural use. |
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| Keywords: | allylation ring opening 2-(bromomethyl)aziridines ammonium salts |
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