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Chromogenic macrocyclic derivatives of azoles—synthesis and properties
Authors:Ewa Wagner-WysieckaEl?bieta Luboch  Marzena KowalczykJan F Biernat
Institution:Department of Chemical Technology, Technical University of Gdańsk, ul. Narutowicza 11/12, 80-952 Gdańsk, Poland
Abstract:The synthesis of macrocyclic chromogenic derivatives of pyrrole and imidazole is described. The complexing properties of these compounds with metal cations were investigated spectrophotometrically in acetonitrile. The synthesized crown ethers were also tested as ion carriers in ion-selective membrane electrodes. The X-ray structure of one isomer of 18-membered pyrrole crown ether is reported.
Keywords:chromoionophores  azole azocrown ethers  synthesis  complexes  spectrophotometric reagents  ion-selective membrane electrodes  X-ray structure
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