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Facile design of a metal-imprinted surface from a poly(vinyl chloride-co-acrylic acid) / poly(propylene glycol) blend
Institution:1. Department of Chemistry, Indiana University, Bloomington, IN 47405, USA;2. Laboratoire d''électrochimie, d''Ingénierie Moléculaire et de Catalyse Rédox (LEIMCR), Faculté de Technologie, Université Sérif-1, Route de Béjaia 19000, Algeria;3. Department of Chemistry, The University of Jordan, Amman 11942, Jordan;1. Laboratoire Réactions et Génie des Procédés, CNRS, Université de Lorraine, ENSIC, 1, rue Grandville, BP 20451, 54001 Nancy Cedex, France;2. National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, P. R. China;3. PhysicoChimie des Processus de Combustion et de l''Atmosphère, CNRS, Université de Lille 1, 59650 Villeneuve d''Ascq, France;4. Department of Chemical & Biomolecular Engineering, North Carolina State University, Raleigh, NC 27695-7905, USA
Abstract:Porous thin films with memory for imprinted metals have been prepared by casting water-THF mixed solutions of a poly(vinyl chloride-co-acylic acid) / poly(propylene glycol) blend. When Cu2+ and Pb2+ ions are imprinted in the cast process, the films retain a memory for the original Cu2+ and Pb2+ ions. The imprinting processes can be thoroughly monitored by FT-IR spectroscopy.
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