Über die Reaktion von W3O mit lod. Darstellung,Kristallstruktur und Eigenschaften von WOI3 |
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Authors: | Bernt Krebs,Claus Brendel,Harald Sch fer |
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Affiliation: | Bernt Krebs,Claus Brendel,Harald Schäfer |
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Abstract: | On the Reaction of W3O with Iodine: Preparation, Crystal Structure, and Properties of WOI3 The novel tungsten oxide iodide WOI3 is obtained from the reaction of the metalrich tungsten oxide W3O (also known as ‘β-tungsten’) with iodine in a sealed glass tube placed in a temperature gradient (440–400°C). In the low-temperature region WOI3 is formed as mouse-grey intergrown needle-like crystals. WOI3 crystallizes in the tetragonal NbOCl3 structure type, space group P42/mnm, with a = 12.346(2), c = 3.765(1) Å (20°C). The crystal structure at – 130°C was determined from single-crystal diffractometer data (R = 0.023). Results of magnetic susceptibility and vibrational spectroscopic measurements are given together with the mass spectrum of WOI3 obtained on heating. |
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