| 过渡金属-碱土金属铜镁异双核配合物的合成、晶体结构和性质研究 |
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| 引用本文： | 陶偌偈,臧双全,于兆文.过渡金属-碱土金属铜镁异双核配合物的合成、晶体结构和性质研究[J].无机化学学报,2002,18(9):907-910. |
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| 作者姓名： | 陶偌偈 臧双全 于兆文 |
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| 作者单位： | 河南大学化学化工学院,开封,475001 |
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| 基金项目： | 河南省杰出青年基金资助项目(No.0040301800)，河南省科委基金资助项目(No.211021300)。 |
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| 摘 要： | The transition metal and alkaline earth metal heterobinuclear complexCuMg(TS)(H2O)·H2O],where TS is the schiff base N,N′-bis(3-carboxylsalidene)trimethylenediamine, was synthesised and its crystal structure was determined by the single-crystal X-ray diffraction method at room temperature. It crystallizes in the monoclinic system, space group P21/n. The lattice parameters are a=12.041(2)?, b=14.736(3)?, c=12.062(2)?, β=118.00(3)°, Z=4 with R1=0.0364. The thermal property and EPR studies of the complex according to crystal structure are also investigated. CCDC: 182408.
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| 关 键 词： | 铜 镁 异双核配合物 热性质 EPR |
| 修稿时间： | 2002年3月2日 |
Synthesis, Molecular Structure and Properties of Heterometal Binuclear Complex, [CuMg(TS) (H2O) ]·H2O |
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| TAO Ruo-Jie,ZANG Shuang-Quan and YU Zhao-Wen.Synthesis, Molecular Structure and Properties of Heterometal Binuclear Complex, [CuMg(TS) (H2O) ]·H2O[J].Chinese Journal of Inorganic Chemistry,2002,18(9):907-910. |
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| Authors: | TAO Ruo-Jie ZANG Shuang-Quan and YU Zhao-Wen |
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| Institution: | Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001,Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001 and Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001 |
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| Abstract: | |
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| Keywords: | copper magnesium heterobinuclear complex thermal property EPR |
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