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GAS PERMEABILITY OF COPOLY(1-TRIMETHYL-SILYL-1-PROPYNE-PENTAMETHYL-DISILYL-1-PROPYNE) MEMBRANE
引用本文:郑国栋,T. Nakagawa,A. Higuchi,K. Nagai. GAS PERMEABILITY OF COPOLY(1-TRIMETHYL-SILYL-1-PROPYNE-PENTAMETHYL-DISILYL-1-PROPYNE) MEMBRANE[J]. 高分子科学, 1992, 0(3): 203-209
作者姓名:郑国栋  T. Nakagawa  A. Higuchi  K. Nagai
作者单位:Changchun Institute of Applied Chemistry,Academia Sinica,Changchun 130022,China,Department Industrial Chemistry,Faculty of Science and Engineering,Meiji University,Kawasaki,JAPAN,Department Industrial Chemistry,Faculty of Science and Engineering,Meiji University,Kawasaki,JAPAN,Department Industrial Chemistry,Faculty of Science and Engineering,Meiji University,Kawasaki,JAPAN
摘    要:The permeability of copoly (1-trimethylsilyl-1-propyne-pentamethyldisilyl-1-propyne) membrane for twelve gases (0_2, N_2, CO_2, H_2, D_2, He, At, CH_4, C_2H_4, C_2H_6, C_3H_6 and C_3H_8) was examined. The basic laws of solution and diffusion of the gases in the membrane were expounded preliminarily. It was found that a linear relationship between logarithm of diffusion coefficient (D) and critical molar volume (V_c) of the gases. The permeation characteristics of the gases in the copoly (1-trimethylsilyl-1-propyne-pentamethyldisilyl-1-propyne) membrane was also discussed.

收稿时间:1990-09-19

GAS PERMEABILITY OF COPOLY(1-TRIMETHYL-SILYL-1-PROPYNE-PENTAMETHYL-DISILYL-1-PROPYNE) MEMBRANE
ZHENG Guodong,T. Nakagawa,A. Higuchi,K. Nagai. GAS PERMEABILITY OF COPOLY(1-TRIMETHYL-SILYL-1-PROPYNE-PENTAMETHYL-DISILYL-1-PROPYNE) MEMBRANE[J]. Chinese Journal of Polymer Science, 1992, 0(3): 203-209
Authors:ZHENG Guodong  T. Nakagawa  A. Higuchi  K. Nagai
Affiliation:Changchun Institute of Applied Chemistry; Academia Sinica; Changchun; China; Department Industrial Chemistry; Faculty of Science and Engineering; Meiji University; Kawasaki; JAPAN
Abstract:The permeability of copoly (1-trimethylsilyl-1-propyne-pentamethyldisilyl-1-propyne) membrane for twelve gases (0_2, N_2, CO_2, H_2, D_2, He, At, CH_4, C_2H_4, C_2H_6, C_3H_6 and C_3H_8) was examined. The basic laws of solution and diffusion of the gases in the membrane were expounded preliminarily. It was found that a linear relationship between logarithm of diffusion coefficient (D) and critical molar volume (V_c) of the gases. The permeation characteristics of the gases in the copoly (1-trimethylsilyl-1-propyne-pentamethyldisilyl-1-propyne) membrane was also discussed.
Keywords:Gas permeability  Copoly (1-trimethylsilyl-1-propyne-pentamethyldisilyl-1-propyne)   Membrane.
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