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复相系平衡条件及平衡稳定性条件的分析
引用本文:曾丹苓.复相系平衡条件及平衡稳定性条件的分析[J].工程热物理学报,1996(1).
作者姓名:曾丹苓
作者单位:重庆大学热力工程系
摘    要:复相系平衡条件及平衡稳定性条件的分析曾丹苓(重庆大学热力工程系重庆630044)关键词复相系,平衡条件,平衡稳定性条件1引言汽液相变是工程上常见的现象,它是一个复杂的物理过程,涉及到传热传质、相转变、表面现象、流体流动及工质热物性等领域,但从热力学的...

关 键 词:复相系,平衡条件,平衡稳定性条件

AN ANALYSIS ON EQUILIBRIUM AND STABILITY CONDITIONS IN MULTI-PHASE SYSTEMS
ZENG Daming.AN ANALYSIS ON EQUILIBRIUM AND STABILITY CONDITIONS IN MULTI-PHASE SYSTEMS[J].Journal of Engineering Thermophysics,1996(1).
Authors:ZENG Daming
Abstract:The present paper is devoted to the analysis of equilibrium and stability conditions in multi-phase systems. The conditions for systems with one mode of work (expansion work)or two modes of it (expansion and surf actal work) are derived in detail. It is asserted by the author that the spinodal line orresponding to the homogeneous system can only be applied to distinguish the accesstable (stable and metastable) states from unaccessible (unstable)ones. Thus it should be differenciated from the phase boundary. The formulas obtained in the paper show that the marginal stability line for homogeneous nucleation will move away from spinodal line in state diagram.
Keywords:multi-phase system  equilibrium condition  stability condition  Spinodal line  
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