Ionothermal syntheses of two new 2D metal-organic frameworks: (EMIM)2[M(Pydc)2] (M = Co,Zn) |
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| Authors: | J. W. Ji G. X. Han Z. B. Han |
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| Affiliation: | (1) College of Chemistry, Liaoning University, Shenyang, 110036, P.R. China |
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| Abstract: | Two new coordination polymers, (EMIM)2[M(Pydc)2] (M is Co, Zn; EMIM is 1-ethyl-3-methylimidazolium; H2Pydc is 2,5-pyridinedicarboxylic acid), have been synthesized through the reaction of cobalt or zinc nitrate with H2Pydc in the ionic liquid medium. The structures exhibit a two-dimensional 4.4-network with the imidazolium cations, acting as charge compensating agent, located between the layers of the coordination anion polymeric frameworks. The article is published in the original. |
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