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X-ray fluorescence determination of bromine in halogenated organic compounds using quasisolid emitters
Authors:L. P. Eksperiandova  A. I. Fedorov  Ya. N. Makarovskaya
Affiliation:(1) Institute for Single Crystals, National Academy of Sciences of Ukraine, pr. Lenina 60, Kharkov, 61001, Ukraine
Abstract:A series of quasi-solid emitters is proposed for the X-ray fluorescence determination of bromine in different bromine-containing compounds. It is shown that sucrose-based glasses are the best emitters for analyzing alkali solutions of halogenated organic compounds, saccharose-based glasses and polymer films are best for analyzing powder samples, and organic gels offer most promise for analyzing liquid (at normal conditions) samples. It is noted that the proposed method can expand the possibilities of commercially produced element analyzers, which are currently intended for determining only C, H, O, N, and S in organic compounds and cannot be used for determining halogens.
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