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Novel crown-containing 3-styryl derivatives of oligothiophenes: synthesis,structure, and optical and electrochemical characteristics
Authors:Lukovskaya  E. V.  Bobyleva  A. A.  Fedorova  O. A.  Fedorov  Yu. V.  Anisimov  A. V.  Didane  Y.  Brisset  H.  Fages  F.
Affiliation:(1) Clinical Chemistry Unit, Department of Chemistry and Nutritional Deficiency Disorders, Animal Health Research Institute, Dokki, Giza, 12618, Egypt;(2) Department of Environmental basic science, Institute of Environmental studies and Research, Ain Shams University, Abbassia, Cairo, 11566, Egypt;(3) Central lab of Ain Shams University, Abbassia, Cairo, 11566, Egypt;
Abstract:
A method for the synthesis of the 3-substituted polythiophene derivatives including two crown-containing styryl fragments was proposed. The optical properties of the obtained compounds are characterized by the presence of intense absorption and fluorescence bands. The oxidation to the thiophene derivatives involves the crown-containing styryl fragment and should be sensitive to the presence of the metal cation in the crown ether cavity.
Keywords:
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