| 一维链状配位聚合物[Cd(N-MeIM)2(SCN)2]n的结构表征和电化学性能研究(英) |
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| 引用本文： | 刘法谦,建方方,汪庆祥,陆路德,杨绪杰,汪信.一维链状配位聚合物[Cd(N-MeIM)2(SCN)2]n的结构表征和电化学性能研究(英)[J].无机化学学报,2005,21(11):1697-1700. |
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| 作者姓名： | 刘法谦 建方方 汪庆祥 陆路德 杨绪杰 汪信 |
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| 作者单位： | 南京理工大学材料化学实验室，南京 210094,青岛科技大学新材料与功能配合物实验室，青岛 266042,青岛科技大学新材料与功能配合物实验室，青岛 266042,南京理工大学材料化学实验室，南京 210094,南京理工大学材料化学实验室，南京 210094,南京理工大学材料化学实验室，南京 210094 |
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| 基金项目： | 山东省自然科学基金（No.Y2002806）资助. |
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| 摘 要： | A novel cadmium(Ⅱ) isothiocyanate complex Cd(N-MeIM)2(SCN)2]n(N-MeIM=N-methylimidazole) has been prepared and characterized by spectroscopic analysis and crystallographic method. The title compound crystallize in the Triclinic system, space group P1, with lattice parameters a=0.589 50(12) nm, b=0.785 70(16) nm, c=0.882 00(18) nm, α=110.98(3)°, β=106.49(3)°, γ=95.08(3)°, and Z=1. The title compound exhibits an infinite chain structure in which each pair of Cd atoms is bridged by two η-1,3-SCN- groups. The unique Cd atom lies on an inversion centre and the coordination sphere is completed by two N-MeIM N atoms to form a CdS2N4 octahedron. The polymeric chains are further extended into three-dimensional network via π…π stackings interactions between the imidazole rings. The cyclic voltammetry behaviors of the compound on glass carbon electrode showed a typical irreversible process. CCDC: 265283.
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| 关 键 词： | 镉(Ⅱ)配合物 π…π 堆积 循环伏安 配位聚合物 |
| 文章编号： | 1001-4861(2005)11-1697-04 |
| 收稿时间： | 2005-03-22 |
| 修稿时间： | 2005-07-14 |
Structure Characterizations and Electrochemical Property of a Novel One-dimensional Coordination Polymer [Cd(N-MeIM)2(SCN)2]n |
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| LIU Fa-Qian,JIAN Fang-Fang,WANG Qing-Xiang,LU Lu-De,YANG Xu-Jie and WANG Xin.Structure Characterizations and Electrochemical Property of a Novel One-dimensional Coordination Polymer [Cd(N-MeIM)2(SCN)2]n[J].Chinese Journal of Inorganic Chemistry,2005,21(11):1697-1700. |
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| Authors: | LIU Fa-Qian JIAN Fang-Fang WANG Qing-Xiang LU Lu-De YANG Xu-Jie and WANG Xin |
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| Institution: | Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science & Technology, Qingdao 266042,New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science & Technology, Qingdao 266042,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094 and Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094 |
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