Headspace gas chromatographic separation of toxic organic impurities from air |
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| Authors: | L. N. Balyatinskaya V. N. Filimonov N. N. Garkavaya |
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| Affiliation: | (1) Department of General and Inorganic Chemistry, Belgorod Technological Academy of Building Materials, 46, ul. Kostiukova, 308012 Belgorod, Russia;(2) Department of Analytical Chemistry, Novomoskovsk Institute of Russian Chemico-Technological Mendeleev University, 8, ul. Druzhby, 301670 Novomoskovsk, Tula region, Russia |
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| Abstract: | Summary To determine toxic organic compounds (methanol, ethanol, n-propanol, acetone, methyl ethyl ketone, methyl isobutyl ketone) in air a method was developed for their headspace gas chromatographic analysis with preconcentration in n-butanol (alcohols) and in n-pentanol (ketones). The distribution coefficients of analytes in the air-absorbent system have been measured: 1051 (MeOH), 5630 (EtOH), 6773 (n-PrOH), 307 (Me2CO), 580 (MeCOEt), 1035 (MeCOBu-i). The minimum detectable level (mg m−3) was determined as low as 0.9 (MeOH), 4.0 (EtOH), 0.9 (n-PrOH), 0.2 (Me2CO), 0.1 (MeCOEt), 0.4 (MeCOBu-i). The method was effectively used for gas effluent air control in the workplace and in the atmosphere. Presented at the 21st ISC held in Stuttgart, Germany, 15th–20th September, 1996 |
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| Keywords: | Gas chromatography Headspace sampling Alcohols, ketones Air analysis |
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