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6′,6″-二吡啶基-2,2′:4′,4″:2″,2′′′-四联吡啶稀土配合物的合成、表征及荧光性质研究(英)
引用本文:唐瑜,张正华,谭民裕,刘伟生.6′,6″-二吡啶基-2,2′:4′,4″:2″,2′′′-四联吡啶稀土配合物的合成、表征及荧光性质研究(英)[J].无机化学学报,2005,21(11):1730-1734.
作者姓名:唐瑜  张正华  谭民裕  刘伟生
作者单位:兰州大学化学化工学院,兰州,730000
基金项目:国家自然科学基金资助项目(No.20401008)
摘    要:Two series of solid complexes of rare earth nitrates and picrates with the “back-to-back” terpyridine, 6′,6″-bis(2-pyridyl)-2,2′:4′,4″:2″,2′′′-quaterpyridine (L) have been synthesized. These complexes have been characterized by elemental analysis, conductivity measurements, thermal analysis and IR spectroscopy. At the same time, the luminescent properties of the Eu(Ⅲ) and Tb(Ⅲ) complexes were also studied.

关 键 词:6′  6″-二吡啶基-2  2′:4′  4″:2″  2′′′-四联吡啶    稀土配合物    荧光性质
文章编号:1001-4861(2005)11-1730-05
收稿时间:2005-03-28
修稿时间:7/6/2005 12:00:00 AM

Synthesis and Luminescent Properties of Rare Earth Complexes of 6',6"-Bis(2-pyridyl)-2,2:4',4":2",2('")-quaterpyridine
TANG Yu,ZHANG Zheng-Hu,TAN Min-Yu and LIU Wei-Sheng.Synthesis and Luminescent Properties of Rare Earth Complexes of 6',6"-Bis(2-pyridyl)-2,2:4',4":2",2('")-quaterpyridine[J].Chinese Journal of Inorganic Chemistry,2005,21(11):1730-1734.
Authors:TANG Yu  ZHANG Zheng-Hu  TAN Min-Yu and LIU Wei-Sheng
Institution:College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000,College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000,College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000
Abstract:Two series of solid complexes of rare earth nitrates and picrates with the "back-to-back" terpyridine, 6',6"-bis(2-pyridyl)-2,2':4',4":2",2('")-quaterpyridine (L) have been synthesized. These complexes have been char acterized by elemental analysis, conductivity measurements, thermal analysis and IR spectroscopy. At the same time, the luminescent properties of the Eu(Ⅲ) and Tb(Ⅲ) complexes were also studied.
Keywords:6'  6"-bis(2-pyridyl)-2  2'  4'  4"  2"  2('")-quaterpyridine  rare earth complexes  luminescent properties
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