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Enthalpies of dilution of aqueous Li2B4O7 solutions at 298.15 K and application of ion-interaction model
Authors:Guoyin Yin  Yan Yao  Baojuan Jiao  Shengli Gao
Institution:a Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008,China
b The Graduate School of Chinese Academy of Sciences, Beijing 100039,China
c Department of Chemistry, Northwest University, Xi’an 710069, China
Abstract:The enthalpies of dilution have been measured for aqueous Li2B4O7 solutions from 0.0212 to 2.1530 mol kg−1 at 298.15 K. The relative apparent molar enthalpies, L?, and relative partial molar enthalpies of the solvent and solute, View the MathML source and View the MathML source were calculated. The thermodynamic properties of the complex aqueous solutions were represented with a modified Pitzer ion-interaction model.
Keywords:Aqueous Li2B4O7  Enthalpy of dilution  Relative apparent molar enthalpy  Relative partial molar enthalpy  Ion-interaction model
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