Ultra-fast microwave enhanced reversible addition-fragmentation chain transfer (RAFT) polymerization: monomers to polymers in minutes |
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Authors: | Brown Steven L Rayner Christopher M Graham Susan Cooper Andrew Rannard Steven Perrier Sébastien |
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Affiliation: | University of Leeds, Woodhouse Lane, Leeds, UKLS2 9JT. |
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Abstract: | Microwave mediated RAFT polymerization leads to ultra-fast polymerizations, whilst keeping excellent control over molecular weights and molecular weight distributions; this is the first example of such a dramatic effect of microwaves on living radical polymerization kinetics, and it shows the potential for chemists to produce very well controlled polymers in a matter of minutes. |
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