| 有机金属化合物的振动光谱(Ⅱ)——1,1′-二甲基环戊二烯铁夹心化合物振动光谱的简正坐标计算 |
| |
| 引用本文： | 刘举正,冯艳,姜世梅,赵文运,梁映秋.有机金属化合物的振动光谱(Ⅱ)——1,1′-二甲基环戊二烯铁夹心化合物振动光谱的简正坐标计算[J].物理化学学报,1988,4(6):578-586. |
| |
| 作者姓名： | 刘举正 冯艳 姜世梅 赵文运 梁映秋 |
| |
| 作者单位： | Institute of Theoretical Chemistry; Jilin University; Chang Chun |
| |
| 摘 要： | 测定了(CH_3Cp)_2Fe(Cp=C_5H_4~-)夹心化合物的Fourier变换红外光谱和激光Raman光谱, 并做了指认, 将G-F矩阵法计算得到的Cp_2M(M=Mn,Fe,Ru)夹心化合物的一套力常数, 完整地转移到该分子上, 计算得到的振动光谱频率与测得的基本一致。
|
| 收稿时间： | 1987-03-28 |
| 修稿时间： | 1987-10-26 |
THE VIBRATIONAL SPECTRA OF ORGANOMETALLIC COMPOUNDS (Ⅱ) FT-INFRARED,LASER RAMAN SPECTRA AND NORMAL COORDINATE CALCULATION FOR 1,1'-DIMETHYLFERROCENE |
| |
| Liu Juzheng,Feng Yan,Jiang Shimei,Zhao Wenyun,Liang Yinqiu.THE VIBRATIONAL SPECTRA OF ORGANOMETALLIC COMPOUNDS (Ⅱ) FT-INFRARED,LASER RAMAN SPECTRA AND NORMAL COORDINATE CALCULATION FOR 1,1'-DIMETHYLFERROCENE[J].Acta Physico-Chimica Sinica,1988,4(6):578-586. |
| |
| Authors: | Liu Juzheng Feng Yan Jiang Shimei Zhao Wenyun Liang Yinqiu |
| |
| Institution: | Institute of Theoretical Chemistry; Jilin University; Chang Chun |
| |
| Abstract: | FT-IR and Laser Raman spectra of (CH_3Cp)_2Fe have been measured. On the basis of qualitative assignment the force constants of Cp_2M(M=Mn,Fe,Ru) obtained by G-F matrix have been translated to the molecule of (CH_3Cp)_2Fe, only the metal coordinate force constants have been adjusted. The same method of G-F matrix has been used for calculating the vibrational spectra frequencies of (CH_3Cp)_2Fe, the result is consistent with the observal one. |
| |
| Keywords: | |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《物理化学学报》浏览原始摘要信息 |
| 点击此处可从《物理化学学报》下载免费的PDF全文 |
|
