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Mechanism of Dealumination of NaY Zeolite with Oxalic Acid
引用本文:Hui LIU, Xing Yun LIU, Xuan Wen LI, Xiao Jie XU(College of Chemistry and Molecular Engineering,Peking University,Beijing 100871). Mechanism of Dealumination of NaY Zeolite with Oxalic Acid[J]. 中国化学快报, 1998, 0(8)
作者姓名:Hui LIU   Xing Yun LIU   Xuan Wen LI   Xiao Jie XU(College of Chemistry and Molecular Engineering  Peking University  Beijing 100871)
作者单位:College of Chemistry and Molecular Engineering,Peking University,Beijing 100871
摘    要:RemovalofalundnumfromNaYzeolitewithacidisanimportantprocessinthemodificationofzeolite.ItisdifficulttoremovealundnumfromNaYzeolitedirectlywithacidwhilekeepinghighcrystallinity.Intheworkreportedhere,alundnumisremoveddirectlyfromNaYwithoxalicacidandthemodifiedzeolitekeepshighcrystallinity.Reactionconditions:CSBlreflux,acidaddedin3ondn,allowedtoreactfor3OAnn.CSB2reflux,acidaddedrapidly,allowedtoreactfor3Owhn.CS2525-C,acidaddedraPidly,allowedtoreactfor3Omin.CSA25"C,acidaddedin3omin,a1lowe…


Mechanism of Dealumination of NaY Zeolite with Oxalic Acid
Hui LIU, Xing Yun LIU, Xuan Wen LI, Xiao Jie XU. Mechanism of Dealumination of NaY Zeolite with Oxalic Acid[J]. Chinese Chemical Letters, 1998, 0(8)
Authors:Hui LIU   Xing Yun LIU   Xuan Wen LI   Xiao Jie XU
Abstract:Dealundnated Y zeolite with high crystallinity is obtained from Ner zeolite by treatment with oxalic acid in a buffering system. The effect of dealumination conditions on the degree of dealumination and the crystallinity of the reformed zeolite is discussed. A mechanism for the reaction is proposed.
Keywords:NaY zeolite  oxalic acid  dealumination mechanism
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