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Mass-analyzed threshold ionization spectroscopy of deuterium-substituted isotopomers of o-fluoroaniline and m-fluoroaniline cations |
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| Authors: | Shih Chang Yang Wen Bih Tzeng |
| Institution: | aInstitute of Atomic and Molecular Sciences, Academia Sinica, P.O. Box 23-166, 1 Section 4, Roosevelt Road, Taipei 10617, Taiwan;bTaiwan International Graduate Program, Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan;cDepartment of Chemistry, National Taiwan Normal University, 88, Section 4, Roosevelt Road, Taipei 11677, Taiwan |
| Abstract: | We applied the resonant two-photon ionization and mass-analyzed threshold ionization techniques to record the vibronic and cation spectra of deuterium-substituted isotopomers of o-fluoroaniline (OFA) and m-fluoroaniline (MFA). The origins of the S1 ← S0 electronic transitions and adiabatic ionization energies of these isotopomers were precisely determined. |
| Keywords: | Resonant two-photon ionization Threshold ionization Vibronic spectra Cation spectra Deuterium substitution Fluoroaniline |
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