| (5,7,7,12,14,14-六甲基-1,4,8,11-四氮杂环十四-4,11-二烯)合镍双(O,O'-二烃基二硫代磷酸酯)的合成与研究 |
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| 引用本文： | 谢斌,吴士业.(5,7,7,12,14,14-六甲基-1,4,8,11-四氮杂环十四-4,11-二烯)合镍双(O,O'-二烃基二硫代磷酸酯)的合成与研究[J].高等学校化学学报,1998,19(1):74-77. |
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| 作者姓名： | 谢斌 吴士业 |
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| 作者单位： | 1. 四川轻化工学院基础部, 自贡, 643033;
2. 四川轻化工学院轻工系, 自贡, 643033 |
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| 基金项目： | 四川省科委重点科研项目基金 |
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| 摘 要： | 合成了4个含四氮杂大环配体和O,O'-二烃基二硫代磷酸根的镍配合物Ni(hmtade){SSP(OR)2}2](hmtade=5,7,7,12,14,14-六甲基-1,4,8,11-四氮杂环十四-4,11-二烯;R=C6H5,2-naphthyl,C6H5CH2CH2,cyclohexyl),用元素分析、摩尔电导、红外光谱和1H NMR、31PNMR、电子光谱及差热分析对其结构进行了表征.研究结果表明:配合物均为非电解质,O,O'-二烃基二硫代磷酸根作为单齿配体对镍中心配位.对四氮杂大环的构型进行了讨沦.
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| 关 键 词： | 四氮杂大环 O O'-二烃基二硫代磷酸酯 配位 构型 |
| 收稿时间： | 1997-01-26 |
| 修稿时间： | 1997年1月26日 |
Synthesis and Characterization of (5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dieno)Nickel Bis(O,O'-dialkyldithiophosphate) |
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| XIE Bin,WU Shi-Ye.Synthesis and Characterization of (5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dieno)Nickel Bis(O,O'-dialkyldithiophosphate)[J].Chemical Research In Chinese Universities,1998,19(1):74-77. |
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| Authors: | XIE Bin WU Shi-Ye |
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| Institution: | 1. Department of Basic Science, Sichuan Institute of Light Industry and Chemical Technology, Zigong, 643033;
2. Department of Light Industry, Sichuan Institute of Light Industry and Chemical Technology, Zigong, 643033 |
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| Abstract: | Four nickel complexes Ni (hmtade) {SSP (OR)2}2] (hmtade=5, 7, 7, 12, 14, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradeca-4, 11-diene; R=phenyl, 2-naphthyl, 2-phenylethyl and cyclohexyl) were synthesized and characterized by elemental analysis, molar conductivity, infrared spectra, electronic spectra, NMR spectra (1H and 31P) and TG-DTA analysis. The results indicate that all complexes are non-electrolysis in DMSO and O,O'-dialkyldithiophosphoric acid radicals as monodentate ligands coordinate to nickel atom. The tetraazamacrocyclic configuration and the TG-DTA curves of complexes are also discussed. |
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| Keywords: | Tetraazamacrocycle O O' -Dialkyldithiophosphate Coordination Configuration |
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