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Synthesis and spectral characteristics of 2-aryl-6-methyl-and 2-aryl-6-benzyl-4,8a-diphenylperhydro[1,3,2]dioxaborinino[5,4-c]pyridines
Authors:Le Tuan Anh  K. B. Polyanskiy  J. A. Mamyrbekova  A. T. Soldatenkov  S. A. Soldatova  V. V. Kurilkin  P. B. Terentiev
Affiliation:1. Peoples’ Friendship University of Russia, Moscow, 117198, Russia
2. ChemBridge Corporation, Moscow, 119048, Russia
3. Abobo-Adjame University, Abidjan, C?te D’Ivoire
4. M. V. Lomonosov Moscow State University, Moscow, 119899, Russia
Abstract:
Aryl-N-methyl-and aryl-N-benzyl-B-substituted 4,8a-diphenylperhydro[1,3,2]dioxaborinino[5,4-c]pyridines, which are representatives of a new class of bicyclic compounds containing four heteroatoms, were synthesized from N-methyl-and N-benzyl-3-(α-hydroxybenzyl)-4-phenyl-γ-piperidols by cyclocondensation with arylboronic acids. The 1H NMR and mass spectra of these compounds were examined as well as mass spectra of previously obtained analogs. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1253–1259, August, 2008.
Keywords:N-alkyl-2,4,8a-triarylperhydro[1,3,2]dioxaborinino[5,4-c]pyridines  arylboronic acids  3-(α  -hydroxybenzyl)-4-phenyl-γ  -piperidols  mass spectra
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