| Synthesis and Crystal Structure of an Ionic Compound [Fe(CN)_6(phCH_2NC_5H_5)3]·(H_2O)_4 |
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| 引用本文： | 杜巧云,辛凌云,李云平.Synthesis and Crystal Structure of an Ionic Compound [Fe(CN)_6(phCH_2NC_5H_5)3]·(H_2O)_4[J].结构化学,2007,26(7):850-854. |
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| 作者姓名： | 杜巧云 辛凌云 李云平 |
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| 作者单位： | Department of Chemistry Luoyang Normal University，Department of Chemistry Luoyang Normal University，Department of Chemistry Luoyang Normal University，Luoyang 471022 China，Luoyang 471022 China，Luoyang 471022 China |
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| 摘 要： | A novel ionic compound Fe(CN)6(phCH2NC5H5)3]·(H2O)4(Mr = 794.71) has been synthesized and its structure was characterized by IR, elemental analysis and X-ray diffraction. The compound crystallizes in monoclinic, space group P21/c with a = 10.837(2), b = 16.551(3), c = 23.402(5) , β = 97.531(4)o, V = 4161.0(15) A3, Z = 4, Dc = 1.269 g/cm3, F(000) = 1668, μ = 0.414 mm-1, R = 0.0479 and wR = 0.1232. The building unit of the title compound consists of three (phCH2N+C5H5) ions, one Fe(CN)6]3- anion and four water molecules. According to the structural analysis, Fe(CN)6]3- are linked together by O–H···N and O–H···O hydrogen bonds, but Fe(CN)6]3- and (phCH2N+C5H5)3] ions are bound by electrostatic force to form an ionic compound.
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Synthesis and Crystal Structure of an Ionic Compound [Fe(CN)_6(phCH_2NC_5H_5)3]·(H_2O)_4 |
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| DU Qiao-Yun,XIN Ling-Yun,LI Yun-Ping,.Synthesis and Crystal Structure of an Ionic Compound [Fe(CN)_6(phCH_2NC_5H_5)3]·(H_2O)_4[J].Chinese Journal of Structural Chemistry,2007,26(7):850-854. |
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| Authors: | DU Qiao-Yun XIN Ling-Yun LI Yun-Ping |
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| Abstract: | A novel ionic compound Fe(CN)6(phCH2NC5H5)3]·(H2O)4(Mr = 794.71) has been synthesized and its structure was characterized by IR, elemental analysis and X-ray diffraction. The compound crystallizes in monoclinic, space group P21/c with a = 10.837(2), b = 16.551(3), c = 23.402(5) , β = 97.531(4)o, V = 4161.0(15) A3, Z = 4, Dc = 1.269 g/cm3, F(000) = 1668, μ = 0.414 mm-1, R = 0.0479 and wR = 0.1232. The building unit of the title compound consists of three (phCH2N+C5H5) ions, one Fe(CN)6]3- anion and four water molecules. According to the structural analysis, Fe(CN)6]3- are linked together by O–H···N and O–H···O hydrogen bonds, but Fe(CN)6]3- and (phCH2N+C5H5)3] ions are bound by electrostatic force to form an ionic compound. |
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| Keywords: | N-benzyl-pyridine ferricyanic anion crystal structure supramolecular ionic compound |
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