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Intercalation of paramagnetic compounds in graphite fluoride with the composition C2Fx
Authors:N F Yudanov  E G Boguslavskii  I I Yakovlev  S P Gabudar
Institution:1. Academy of Sciences of the USSR, Novosibirsk
Abstract:
1.  A method has been developed for the intercalation of solid substances from solutions in organic solvents into graphite fluoride C2Fx.
2.  Molecules of inserted paramagnetic copper complexes and nitroxyl radicals assume oriented positions between the structural layers in graphite fluoride.
3.  The planes of molecules of bis-chelate Cu(II) complexes with acetylacetone, o-hydroxyquinoline, and phenylsalicylaldimine were determined to lie parallel to the C2Fx planes.
4.  A method has also been suggested for the preparation of samples from C2Fx·yA compounds with a higher degree of texturizing (more nearly complete orientation) than can be achieved by pelletizing.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 272–276, February, 1988.
Keywords:
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