EPR study of the dinitrogen tetroxide dissociation in organic solvents |
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| Authors: | Karol Miąskiewicz Zbigniew Kęcki |
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| Institution: | (1) Laboratory of Molecular Interactions, Department of Chemistry, University of Warsaw, PL-02-093 Warszawa, Poland |
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| Abstract: | The dinitrogen tetroxide homolytical dissociation constants K
DIS
are determined in organic solvents. The values are the highest in non-donor and the lowest in n-donor solvents. The variations of K
DIS
with solvent are interpreted in terms of electron donor-acceptor interactions between dinitrogen tetroxide and electron donor molecules. |
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| Keywords: | N2O4 dissociation equilibrium EDA interactions EPR of NO2 |
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