Design of polyethers,thioethers, and amines with pendent iron moieties

Soluble organoiron polyethers, thioethers, and amines were synthesized via nucleophilic aromatic substitution reactions. The synthesis of these classes of organometallic polymers involved either the reaction of cyclopentadienyliron complexes of dichloroarenes with various oxygen and sulfur dinucleophiles or the reaction of ether‐ or amine‐containing diiron complexes with dithiols. Polymerization reactions with the diiron complexes gave rise to organoiron polymers with alternating ether/thioether or amine/thioether bridges. Removal of the iron moieties from the backbone of these polymers allowed for the production of the corresponding organic materials. Furthermore, the organometallic polymers had much higher solubilities than their organic analogues. Thermogravimetric analysis of the organoiron polymers indicated that the polymers lost their metallic moieties at approximately 200 °C, whereas degradation of the polymer backbones occurred around 500 °C. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 1216–1231, 2001