On the short carbonyl bond in bis[μ‐1,2‐benzisothiazol‐3(2H)‐one 1,1‐dioxido‐κ2N:O]bis{[1,2‐benzisothiazol‐3(2H)‐one 1,1‐dioxido‐κN]bis(imidazole)copper(II)} |
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Authors: | Pan
e Naumov,Gligor Jovanovski,Sheng‐Zhi Hu,Il‐Hwan Suh,Ibrahim Abdul Razak,Suchada Chantrapromma,Hoong‐Kun Fun,Seik Weng Ng |
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Affiliation: | Panče Naumov,Gligor Jovanovski,Sheng‐Zhi Hu,Il‐Hwan Suh,Ibrahim Abdul Razak,Suchada Chantrapromma,Hoong‐Kun Fun,Seik Weng Ng |
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Abstract: | ![]() The short carbonyl bond in the title compound, [Cu2(C7H4NO3S)4(C3H4N2)4] [Liu, Huang, Li & Lin (1991). Acta Cryst. C 47 , 41–43], is an artifact of disorder in the isothiazol‐3(2H)‐one 1,1‐dioxide part of the 1,2‐benzisothiazol‐3(2H)‐one entity. In the present redetermination, all bond dimensions in the centrosymmetric dinuclear molecule are normal. The five‐coordinate Cu atom shows trigonal–bipyramidal coordination. Hydrogen bonds from the imidazole donor ligand link adjacent molecules into a two‐dimensional layer structure. |
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