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catena‐Poly­[[bis­(thio­cyanato‐N)lead(II)]‐μ‐1,2‐bis(4‐pyridyl)ethane‐N:N′]
Authors:Yun‐Yin Niu  Hong‐Wei Hou  Qian‐Feng Zhang  Xin‐Quan Xin  Hoong‐Kun Fun  Suchada Chantrapromma  Ibrahim Abdul Razak
Abstract:In the title coordination polymer, Pb(NCS)2(C12H12N2)], the coordination geometry about the PbII atom is a distorted octahedron, composed of two N atoms from bpe ligands bpe is 1,2‐bis(4‐pyridyl)ethane], two other N atoms from NCS? groups and two neighbouring S atoms through short contacts. The trans‐bpe ligands act as bridges between two PbII centres resulting in the formation of a linear chain. The terminal S atoms of the NCS? ligands make short contacts with the PbII atom of neighbouring chains to form an infinite two‐dimensional polymeric structure.
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