| Influence of reagent vibration on the stereodynamics of the Li + HF → LiF + H reaction |
| |
| 作者姓名： | 李淑娟 石英 解廷献 金明星 |
| |
| 作者单位： | (1)Department of Physics, Dalian Jiaotong University, Dalian 116028, China; (2)Institute of Atomic and Molecular Physics, Jilin University, Changchun 130012, China |
| |
| 基金项目： | Project supported by Jilin University, China (Grant No. 419080106440), the Chinese National Fusion Project for ITER (Grant No. 2010GB104003), and the National Natural Science Foundation of China (Grant No. 10974069). |
| |
| 摘 要： | We investigate the influence of reagent vibration on the stereodynamics of the title reaction by the quasi-classical trajectory on the Aguado-Paniagua2-potential energy surface developed by Aguado et al. (J. Chem. Phys. 1997 106 1013). The cross sections and reaction probability as functions of the reagent vibration are calculated in the centre-of-mass frame. The product angular distributions of p(θr), p(φr), and p(θr, φr), which reflect the vector correlation, are also presented and discussed. The results indicate that the vector properties are sensitively affected by the vibrational excitation.
|
| 收稿时间： | 2011-05-06 |
|
| 点击此处可从《中国物理 B》浏览原始摘要信息 |
|
点击此处可从《中国物理 B》下载免费的PDF全文 |
|
