One-pot enantioselective formation of eight-membered rings from alkenyl Fischer carbene complexes and ketone enolates |
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| Authors: | Barluenga José Diéguez Alejandro Rodríguez Félix Flórez Josefa Fañanás Francisco J |
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| Affiliation: | Instituto Universitario de Química Organometálica Enrique Moles, Unidad Asociada al C.S.I.C., Universidad de Oviedo, Julián Clavería, 8, E-33071 Oviedo, Spain. barluenga@sauron.quimica.uniovi.es |
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| Abstract: | ![]()
Eight-membered carbocycles with up to five new stereogenic centers are enantioselectively obtained following a one-pot procedure that involves the coupling of three components: an alkenyl Fischer carbene complex, a ketone enolate, and allyl lithium. |
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