Direct 13C-13C spin-spin coupling constants in the vinyl group of N-vinylazoles |
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Authors: | A. V. Afonin L. B. Krivdin D. K. Danovich V. K. Voronov L. A. Es'kova B. V. Trzhtsinskaya L. V. Baikalova S. R. Buzilova G. A. Gareev |
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Affiliation: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, 664033 Irkutsk |
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Abstract: | The unshared electron pair of the dicoordinated nitrogen atom introduces a stereospecific contribution to the 13C-13C spin-spin coupling constant (SSCC) in the vinyl group of a series of N-vinylazoles, the value of which depends on the energetics of the unshared pair.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 197–200, February, 1989. |
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