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Direct 13C-13C spin-spin coupling constants in the vinyl group of N-vinylazoles
Authors:A. V. Afonin  L. B. Krivdin  D. K. Danovich  V. K. Voronov  L. A. Es'kova  B. V. Trzhtsinskaya  L. V. Baikalova  S. R. Buzilova  G. A. Gareev
Affiliation:(1) Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, 664033 Irkutsk
Abstract:The unshared electron pair of the dicoordinated nitrogen atom introduces a stereospecific contribution to the 13C-13C spin-spin coupling constant (SSCC) in the vinyl group of a series of N-vinylazoles, the value of which depends on the energetics of the unshared pair.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 197–200, February, 1989.
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