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ESR study of the 1,2-migration of F atoms in polyfluorinated radicals
Authors:V. N. Kovtonyuk  L. S. Kobrina  A. M. Volodin
Affiliation:(1) Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090 Novosibirsk, Russian Federation
Abstract:
The 1,2-migration of the F atom in polyfluorinated cyclohexadienyl radicals generated in the reaction of perfluoro-p-xylene with pentafluorobenzoyl peroxide has been observed directly by ESR.Translated fromIzvestiya Akademii Nauk. Seriya Khitnicheskaya, No. 1, pp. 100–103, January, 1995.
Keywords:pentafluorophenyl radical  polyfluorinated cyclohexadienyl radicals, fluorine 1,2-migration
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