|
|||||
|
|
| 掺杂F-对PbO2阳极性能和电催化活性的影响 | |
| 引用本文： | 赵海燕,曹江林,张鉴清.掺杂F-对PbO2阳极性能和电催化活性的影响[J].无机化学学报,2007,23(12):2079-2084. |
| 作者姓名： | 赵海燕 曹江林 张鉴清 |
| 作者单位： | 1. 河北科技大学理学院,石家庄,050016 2. 浙江大学化学系,杭州,310027 3. 浙江大学化学系,杭州,310027;中国科学院金属研究所,腐蚀与防护国家重点实验室,沈阳,110016 |
| 基金项目： | 中国博士后科学基金;中国科学院金属研究所腐蚀与防护国家重点实验室基金 |
| 摘 要： | 采用热分解-电镀法制备了Ti基PbO2阳极(PbO2阳极)和F-掺杂PbO2阳极(F-PbO2阳极)。应用XRD和SEM技术对这两种电极进行了表征，采用加速电解寿命测试研究了其在硫酸溶液中的电解稳定性。结果表明，F-PbO2阳极的寿命远大于PbO2阳极的寿命，在4-氯苯酚(4-CP)的电催化降解过程中，F-PbO2阳极表现出比PbO2阳极较强的催化活性。本文对F-掺杂提高PbO2阳极性能和电催化活性的机理进行了探讨。并应用高效液相色谱确定了4-CP在F-PbO2阳极上的降解历程。 |
| 关 键 词： | 电催化 F-PbO2阳极 降解 4-氯苯酚 |
| 文章编号： | 1001-4861（2007）12-2079-06 |
| 收稿时间： | 2007-08-13 |
| 修稿时间： | 2007-10-28 |
Effect of Fluorine Ion Doping on Performance and Electrocatalytic Activity of PbO2 Anodes |
|
| ZHAO Hai-Yan,CAO Jiang-Lin and ZHANG Jian-Qing.Effect of Fluorine Ion Doping on Performance and Electrocatalytic Activity of PbO2 Anodes[J].Chinese Journal of Inorganic Chemistry,2007,23(12):2079-2084. | |
| Authors: | ZHAO Hai-Yan CAO Jiang-Lin and ZHANG Jian-Qing |
| Abstract: | Ti-substrate PbO2 and F-doped PbO2(F-PbO2) anodes were prepared by thermal decomposition-electrodeposition technique.The anodes were characterized by XRD and SEM.The electrochemical stability was studied by the accelerated life tests in H2SO4 solution.The results show that the service life of the F-PbO2 anodes is much more longer than that of the undoped anodes.Moreover,the F-PbO2 anodes show a higher degradation rate for 4-chlorphenol(4-CP) than that observed for the PbO2 anodes.The influence of F-doping on the performance and electrocatalytic activity of PbO2 anodes has been discussed.In addition,the degradation mechanism of 4-CP is proposed according to the results of high-performance liquid chromatograph(HPLC). |
| Keywords: | electrocatalysis F-PbO2 anodes degradation 4-chlorphenol |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |
| 点击此处可从《无机化学学报》浏览原始摘要信息 | |
| 点击此处可从《无机化学学报》下载免费的PDF全文 | |