| Synthesis and Crystal Structure of a Mixed （Phthalocyaninato）（porphyrinato） Yttrium Double-decker Complex |
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| 作者姓名： | LU Ji-Tao WANG Hai-Long ZHANG Xiao-Mei |
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| 作者单位： | School of Chemistry ＆ Chemical Technology, Shandong University, Jinan 250100, China |
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| 基金项目： | Supported by the National Natural Science Foundation of China，the Natural Science Foundation of Shandong Province，the Doctoral Foundation of Shandong Province，Independent Iunovation Foundation of SDU is gratefully acknowledged |
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| 摘 要： | The title compound,a mixed(phthalocyaninato)(porphyrinato) yttrium double-decker complex 1,has been synthesized and structurally characterized by X-ray single-crystal diffraction method.Crystal data:monoclinic,space group C2/c,Z = 8,C79H52Cl10N12O4Y,Mr = 1676.74,a = 38.217(3),b = 18.9867(13),c = 26.200(3) ,β = 128.0190(10)°,V = 14977(2) 3,Dc = 1.487 g/cm3,μ(MoKα) = 1.196 mm-1,F(000) = 6808,R = 0.0745 and wR = 0.2208 for observed reflections with I > 2σ(I).X-ray analysis reveals that the coordination polyhedron adopts a slightly distorted square-antiprismatic structure around the metal center.Both phthalocyanine and porphyrin ligands are saucer-shaped,with the skew angle of the two ligand planes approximately 45°.
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| 关 键 词： | 晶体结构 卟啉 酞菁 合成 混合 X射线衍射分析 复合物 钇 |
Synthesis and Crystal Structure of a Mixed (Phthalocyaninato)(porphyrinato) Yttrium Double-decker Complex |
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| LU,Ji-Tao WANG,Hai-Long ZHANG,Xiao-Mei.Synthesis and Crystal Structure of a Mixed (Phthalocyaninato)(porphyrinato) Yttrium Double-decker Complex[J].Chinese Journal of Structural Chemistry,2011,30(6):872-876. |
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| Authors: | LU Ji-Tao WANG Hai-Long ZHANG Xiao-Mei |
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| Institution: | School of Chemistry & Chemical Technology, Shandong University, Jinan 250100, China |
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| Abstract: | The title compound, a mixed (phthalocyaninato)(porphyrinato) yttrium double-decker complex 1, has been synthesized and structurally characterized by X-ray single-crystal diffraction method. Crystal data: monoclinic, space group C2/c, Z = 8, C79H52Cl10N12O4Y, Mr =1676.74, a = 38.217(3), b = 18.9867(13), c = 26.200(3) (A), β = 128.0190(10)°, V= 14977(2) (A)3, Dc= 1.487 g/cm3, μ(MoKa) = 1.196 mm-1, F(000) = 6808, R = 0.0745 and wR = 0.2208 for observed reflections with I ＞ 2σ(Ⅰ). X-ray analysis reveals that the coordination polyhedron adopts a slightly distorted square-antiprismatic structure around the metal center. Both phthalocyanine and porphyrin ligands are saucer-shaped, with the skew angle of the two ligand planes approximately 45°. |
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| Keywords: | crystal structure phthalocyanine porphyrin |
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