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新型PVT性质测试系统的研制
引用本文:杨志强,郝志军,王伟,曾纪珺,张伟,吕剑.新型PVT性质测试系统的研制[J].分析测试技术与仪器,2009,15(4):241-244.
作者姓名:杨志强  郝志军  王伟  曾纪珺  张伟  吕剑
作者单位:西安近代化学研究所,陕西,西安,710065
摘    要:研制了一套新型压力-温度-体积(PVT)性质测试系统.该系统由自行开发的测控软件实时测控,温度测量精度可达±10mK,压力测量系统最大不确定度为±1.2KPa.利用新的测试系统对294~351K温度区间的Hydrofluorocarbons(HFC)-245fa饱和蒸气压进行了研究.实验结果表明,HFC-245fa的测量值与公认文献值的平均偏差小于0.03%,最大偏差小于0.484%,结果与文献值吻合较好.

关 键 词:PVT性质  测试系统  HFC-245fa  饱和蒸气压
收稿时间:2009/8/21 0:00:00
修稿时间:2009/9/16 0:00:00

Development of New High Accuracy PVT Measurement System
YANG Zhi-qiang,HAO Zhi-jun,WANG Wei,ZENG Ji-jun,ZHANG Wei and LU Jian.Development of New High Accuracy PVT Measurement System[J].Analysis and Testing Technology and Instruments,2009,15(4):241-244.
Authors:YANG Zhi-qiang  HAO Zhi-jun  WANG Wei  ZENG Ji-jun  ZHANG Wei and LU Jian
Institution:YANG Zhi - qiang, HAO Zhi - jun, WANG Wei, ZENG Ji - jun, ZHANG Wei, LU Jian( Xi'an Modern Chemistry Research Institute, Xi'an 710065, China)
Abstract:A new experimental system of PVT measurement automatically controlled by a computer has been developed. The overall pressure and temperature uncertainty is about ±1.2 KPa, and ±5 mK, respectively. The vapor pressures of HFC-245fa were measured in the temperature range from 294 to 351 K with the new experimental system, and the experimental results indicated that the average deviation between experimental data and the equation provided in the literature was below 0.03%, and the standard deviation was below 0.484%. Which approved that the new experimental system is reliable.
Keywords:HFC-245fa
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