Abstract: | Solution‐, melt‐, and co‐axial electrospinning are well‐known methods for producing nano‐ and microfibers. The electrospinning of colloids (or colloid‐electrospinning) is a new field that offers the possibility to elaborate multicompartment nanomaterials. However, the presence of colloids in the electrospinning feed further complicates theoretical predictions in a system that is dependent on chemical, physical, and process parameters. Herein, we give a summary of recent important results and discuss the perspectives of electrospinning of colloids for the synthesis and characterization of multicompartment fibers. |